[ sulge aken ]
| Elulookirjeldus (CV) | ||
| 1. | Eesnimi | Ilmar |
| 2. | Perekonnanimi | Koppel |
| 3. | Töökoht | Keemilise füüsika istituut,Tartu Ülikool |
| 4. | Ametikoht | erakorraline professor |
| 5. | Sünniaeg | 16.01.1940 (päev.kuu.aasta) |
| 6. | Haridus | Lõpetas TÜ keemiaosakonna 1963,cum laude |
| 7. | Teenistuskäik | 1967-1975,vanemteadur,TÜ keemilise kineetika ja katalüüsi labor(KKKL) 1976-1987,laborijuhataja,TÜ KKKL 1988-1992,TÜ analüütilise keemia kateedri juhataja,professor 1992-2005,TÜ keemilise füüsika instituudi juhataja,analüütilise keemia professor 2001-2005,TÜ keemiaosakonna juhataja 1996-1997,TÜ Tehnoloogiakeskuse asutaja-juhataja 2004-Eesti TA BGKO juhataja 1974/75 postdok/stazöör,California Ülikool,Irvine 1978/79 külalisprofessor,Briti Columbia Ülikool 1981/82 külalisprofessor,California Ülikool,Irvine 1989/90 külalisuurija,California Ülokool 1994,Madrid,CSIC,külalisprofessor 1999,Kyushu Ülikool,külakisprofessor 1993,1993/4,1995,1996,1998-lühematel perioodidel-külalisuurija 2005-TÜ erakorraline professor |
| 8. | Teaduskraad | keemiakandidaat keemiadoktor |
| 9. | Teaduskraadi välja andnud asutus, aasta |
1969,TÜ 1987,NSVL TA Keemilise Füüsika Instituut,Moskva |
| 10. | Tunnustused | Eesti TA liige,füüsikaline keemia/loodusteadused,1993- EV riiklik preemia keemia ja molekulaarbioloogia alal,1998 EV riiklik preemia pikaajalise tulemusliku teadustöö eest,2005 |
| 11. | Teadusorganisatsiooniline ja –administratiivne tegevus |
EV teaduspreemiate komisjon,1997-2004 SA ETF Nõukogu,1997-2003,2005- TÜ Nõukogu,2001-2003 ESF PESC rahvuslik delegaat,2002-2005 TÜ keemilise kineetika ja katalüüsi labori juhataja,1976-1987 TÜ keemilise füüsika instituudi juhataja 1992-2005 TÜ tehnoloogiakeskuse juhataja ja nõukogu esimees 1996-97 TÜ keemiaosakonna juhataja 2001-2005 Keemia ja materjaliteaduse tippkeskuse juht 2002- PHARE HESR programmi juhtkomitee liige,1995-1999 TÜ analüütilise keemia kateedri juhataja,1988-1992 |
| 12. | Juhendamisel kaitstud väitekirjad |
mihkel kerikmäe, PhD, 2004, juh. ilmar koppel,mihhail danilkin. Some luminescent materials for dosimetric applications and physical research. Tartu Ülikool ivari kaljurand, PhD, 2003, juh. ilmar koppel,ivo leito. Self-consistent acidity scales of neutral and cationic Brönsted acids in acetonitrile and tetrahydrofuran. Tartu Ülikool mare piirsalu, PhD, 2003, juh. ilmar koppel,vilve nummert. Substituent,temperature and solvent effects on the alkaline hydrolysis of substituted phenyl and alkyl esters of benzoic acid. Tartu Ülikool koit herodes, PhD, 2002, juh. ilmar koppel. Solvent effects on UV-vis absorption spectra of some solvatochromic substances in binary solvent mixtures;the preferential solvation model. Tartu Ülikool ivar koppel, PhD, 2001, juh. ilmar koppel,peeter burk. Quantum chemical study of acidity of strong and superstrong Brönsted acids. Tartu Ülikool katrin kollist, PhD, 2001, juh. ilmar koppel,uuve kirso. Interactions between polycyclic aromatic compounds and humic substances. Tartu Ülikool natalia palm, PhD, 2001, juh. ilmar koppel,viktor palm. Specification of the minimum,sufficient and significant set of descriptors for general description of solvent effects. Tartu Ülikool viljar pihl, PhD, 2001, juh. ilmar koppel. The study of the substituent and solvent effects on the acidity of OH and CH acids. Tartu Ülikool ivo leito, PhD, 1997, juh. ilmar koppel. Studies of Brönsted acid-base equilibria in water and non-aqueous media. Tartu Ülikool vahur mäemets, PhD, 1997, juh. ilmar koppel. The 17O and 1H nuclear magnetis resonance study of H2O in individual solvents and its charged clusters in aqueous solutions of electrolytes. Tartu Ülikool peeter burk, DSc, 1994, juh. ilmar koppel. Theoretical Study of Gas-Phase Acid-Base Equilibria. Tartu Ülikool rein pikver, cand, 1986, juh. ilmar koppel,endel lippmaa. The Influence of Structure onthe Ionisation Potentials of Carbonyl Compounds. Tartu Ülikool, Uldo Mölder, cand, 1984, juh. ilmar koppel. The Influence of Structure on the Ionisation Potentials of Compounds with Lone Electron Pairs. Tartu Ülikool |
| 13. | Teadustöö põhisuunad | Happelis-aluselised tasakaalud gaasifaasis ja lahustes,superhapete ja -aluste keemia,solvendiefektid keemias,keemiliste ühendite elektronstruktuuri ja reaktsioonivõime kvantkeemilised arvutused(ab initio,DFT),molekulaardisain,fotoelektron spektroskoopia; Ca 250 publikatsiooni |
| 14. | Jooksvad grandid | ETF5226,Tugevate ja ülitugevate Brönstedi hapete ja aluste happelisuse ja aluselisuse uurimine 2005-242000kr,grandihoidja-I.Koppel Sihtfinantseerimine:0182552s03 Keemiliste ühendite reaktsioonivõime ja omaduste eksperimentaalne ja teoreetiline uurimine,2005a-2530000kr,PI-I.Koppel |
| 15. | Teaduspublikatsioonid |
Kütt,A.;Leito,I.,Kaljurand,I.;Sooväli,L.;Vlasov,V.M.;Yagupolskii,L.M.,Koppel,I.A.A Comprehensive Self-Consistent Spectrophotometric Acidity Scale of Neutral Brönsted Acids in Acetonitrile,J.Org.Chem.,2006,71,2829-2838. Nummert,V.,Piirsalu,M.,Mäemets,V.,Koppel,I.,Kinetic Study of Hydrolysis of Benzoates.Part XXV.Ortho Substituent Effect in Alkaline Hydrolysis of Phenyl Esters of Substituted Benzoic Acids in Water,Collect.Czech.Chem.Commun.2006,71,#1,107-128 Sooväli,L.,Rodima,T.,Kaljurand,I.,Kütt,A.,Koppel,I.A.,Leito,I.,Basicity of some P1 Phosphazenes in Water and in Aqueous Surfactant Solution,Org.Biomol.Chem.2006,4,2100-2105. A.A.Kolomeitsev,I.A.Koppel,T.Rodima,J.Barten,E.Lork,G-V.Röschenthaler,I.Kaljurand,A.Kütt,I.Koppel,V.Mäemets,I.Leito,Guanidinophosphazenes:Design,Synthesis,and Basicity in THF and in the Gas Phase,J.Am.Chem.Soc.,2005,127,17656-17666 Herodes,K.;Leito,I.;Koppel,J;Reichardt,C.;Koppel,I.A.;UV-vis Spectrophotometric Study of the Hydrophilic and Solvatochromic 4-(2,6-diphenyl-4-(pyridin-4-yl)-pyridinium-1-yl)-2,6-bis(pyridin-3-yl)phenolate betaine Dye in Aqueous tetra-n-butylammonium bromide.,J.Phys.Org.Chem.,2005,18,1013-1017 Kaljurand,I.;Kutt,A.;Soovali,L.;Rodima,T.;Maemets,V.;Leito,I.;Koppel,I.A.,Extension of the Self-consistent Spectrophotometric Scale in Acetonitrile to a Full Span of 28 pKa Units:Unification of Different Basicity Scales,J.Org.Chem.,2005,70,1019-1028 Kaljurand,I.;Leito,I.;Rodima,T.;Kütt,A.;Pihl,A.;Rõõm,E.-I.;Sooväli,L.;Mäemets,V.;Pihl,V.;Koppel,I.A.;Mishima,M.;Vlasov,V.M.;Yagupolskii.L.M.;.Self-Consistent Bronsted Acidity and Basicity Scales in Nonaqueous Solvents,KISPOC-XI,Fukuoka ,September 12-15,2005,Proceedings,pp 89-94 Leito,I.;Kaljurand,I.;Rodima,T.;Kütt,A.;Pihl,A.;Rõõm,E.-I.;Sooväli,L.;Mäemets,V.;Pihl,V.;Koppel,I.A.;Self-Consistent Acidity and Basicity Scales in Nonaqueous Solvents,Proc.Estonian Acad.Sci.,2005,54,94-115. Nummert,V.;Piirsalu,M.;Lepp,M.;Mäemets,V.;Koppel,I.Kinetic Study of Alkaline Hydrolysis of Substituted Phenyl Tosylates.XXII.Variation of Ortho Substituent Effect With Solvent, Coll.Czech.Chem.Comm.2005,70,18-222. Nummert,V.;Piirsalu,M;Mäemets,V.;Koppel,I.;Kinetic Study of Hydrolysis of Benzoates.Part XXIV,Variation of the Ortho Substituent Effect With Solvent in the Alkaline Hydrolysis of Substituted Phenyl Benzoates,J.Phys.Org.Chem.2005,18,1138-1144 Ragnarsson,U.;Grehn,L;Koppel,J.;Loog,O.;Tsubrik,O.;Mäeorg,U.;Koppel I.A.;Acidity of di-and diprotected Hydrazine Derivatives in Dimethylsulfoxide and Aspects of their Alkylation,J.Org.Chem.,2005,70,5916-5921 Abboud,J.-L.;Alkorta,I.;Burk,P.;Davalos,J.,Z.;Quintanilla,E.;Della,E.;Koppel,I.A.;Koppel I.,The Enormous Apparent Gas-Phase Acidity of Cubylamine.;Chem.Phys.Lett.;2004,398,560-563. Mölder,U.;Burk,P.;Koppel,I.A.,Quantum Chemical Calculations of Linear Cumulene Chains,J.Mol.Struct(Theochem),2004,712,81-89. Abboud,J.-L.;Koppel,I.A.;Davalos,J.Z.; Burk,P.;Koppel I.;Quintanilla,E.,Protonation of the Cubane in the Gas Phase:A High-Level Ab initio and DFT Study,Angew.Chem.Int.Edit.,2003,42/19,1044-1046 Abboud,J.-L.M.;Koppel,I.A.;Alkorta,I.,Della,E.;Müller,P.;Davalos,J.Z.;Burk,P.;Koppel,I.;Pihl,V.;Quintanilla,E.;Stereoelectronic,Strain,and Medium Effects on the Protonation of Cubylamine,a Janus-like Base.;Angew.Chem.Int.Ed.,2003,42/20,2281-2285. Burk,P.;Leito,I.;Koppel,I.;Koppel,I.A.;Superacidity and Superbasicity of Neutral Bronsted Acids and Bases,KISPOC-X,Fukuoka,Sept.30-Oct 3,Proceedings,pp 19-24 Herodes,K.;Koppel,J.;Reichardt,C.;Koppel,I.A.;UV-visible spectroscopic study of the hydrophilic4-[2,6-diphenyl-4-(pyridin-4-yl]-2,6-bis/pyridin-3-yl)phenolate betaine dye in eight binary solvent mixtures,J.Phys.Org.Chem.,2003,16,626-632 Kaljurand,I.;Rodima,T.;Pihl,A.;Maemets,V.;Leito,I.;Koppel,I.A.;Mishima,M.,Acid-Base Equilibria in Nonpolar Media.4.Expanding the Self-consistent Basicity Scale in THF Medium.Gas-phase Basicities of Phosphazenes,J.Org.Chem.,2003,68,9988-9993. Kaljurand,I.;Rodima,T.;Pihl,A.;Rõõm,E.-I.;Leito,I.;Kütt,A.;Sooväli,L.;Mäemets,V.;Koppel,I.A.;Mishima,M.;Yagupolskii,L.M.,Extending Acidity and Basicity Scales in Nonaqueous Solvents and Gas-phase,KISPOC-X,Fukuoka,Sept 30-Oct 3,2003,Proceedings,pp 216-221 Rõõm,E.-I.;Kaljurand,I.;Leito,I.;Rodima,T.;Koppel,I.A.;Vlasov,V.M.,Acid-Base Equilibria in Nonpolar Media.3.Expanding the Spectrophotometric Acidity Scale in Heptane,J.Org.Chem.,2003,68,7795-7799. Koppel,I.A.;Burk,P.;Koppel,I.;Leito,I.;Generalized Principle of Designing of Neutral Superstrong Brönsted Acids,J.Am.Chem.Soc.,2002,124,5594-5600. Mõlder,U.;Pikver,R.;Koppel,I.I.;Burk,P.;Koppel ,I.A.;Photoelectron Spectra of Molecules.12.Vinyl,Allyl,and Phenyl Ethers and Sulfides.,J.Mol.Struct(Theochem),2002,579,205-220. Rodima,T.;Kaljurand,I.;Pihl,A.;Mäemets,V.;Leito,I.;Koppel,I.A.;Acid-base Equilibria in Nonüpolar Media.2.Self-Consistent Basicity Scale in THF Solution Ranging from 2-Methoxypyridine to EtP1(pyr) Phosphazene.,J.Org.Chem.,2002,67,1873-1881. Yagupolskii,L.M.;Petrik,V.N.;Kondratenko,N.V.;Sooväli,L.;Kaljurand,I.;Leito,I.;Koppel,I.A.,The Immense Acidifying effect of the Supersubstituent =NSO2CF3 on the Acidity of Amides and amidines of Benzoic Acid in Acetonitrile,J.Chem.Soc.Perkin Trans 2,2002,1950-1955. Burk,P.;Sillar,K.;Koppel,I.A.;Gas-Phase Basicities and Proton Affinities of Alkali Metal Oxides and Hydroxides,A theoretical Study,;J.Mol.Struct.(Theochem),2001,54,1-3,223-231 Koppel,I.A.;Koppel,J.;Leito,I.;Koppel,I.;Mishima,M.;Yagupolskii,L.M.;The Enormous Acidifying Effect of Supersubstituents =NSO2CF3 on Acidity of Derivatives of Benzenesulfonamide and para-toluenesulfonamide in the gas-phase and in Dimethylsulfoxide,J.Chem.Soc.Perkin 2,2001,229-232. Koppel,I.A.;Schwesinger,R.;Breuer,T.;Burk,P.;Herodes,K.;Koppel,I.I.;Leito,I.;Mishima,M., Intrinsic Basicities of Phosphorus Imines and Ylides.A Theoretical Study,J.Phys.Chem.A,2001,105,9575-9586. Mölder,U.;Burk,P.;Koppel,I.A.;Quantum Chemical Calculations of Geometries and Gas-Phase Deprotonation Energies of Linear Polyyne Chains,Int.Quant.Chem.;2001,82,73-85. Burk,P.;Koppel,I.A.;Koppel,I.;Leito,I.;Travnikova,O.;Critical Test of Performance of B3LYP Functional for Prediction of Gas-Phase Acidities and Basicities,Chem.Phys.Lett.,2000,232,5-6,482-489. Kaljurand,I.;Rodima,T.;Leito,I.;Koppel,I.A.;Schwesinger,R.;self-Consistent Spectrophotometric Basicity Scale in Acetonitrile Covering range Between Pyridine and DBU,J.Org.Chem.,2002,65,6202-6208. Koppel,I.A.;Burk,P.;Koppel,I.;Leito,I.;Sonoda,T.;Mishima,M.;Gas-Phase Acidities of Some Neutral Superacids:A DFT and Ab initio Study,J.Am.Chem.Soc.,2000,122,5114-5124. Koppel I.A.;Koppel,J.;Pihl,V.;Leito,I.;Mishima,M.;Vlasov,V.M.;Yagupolskii,L.M.;Taft,R.W.;Comparison of Brönsted Acidities of Neutral CH acids in Gas Phase and Dimethyl Sulfoxide,J.Chem.Soc,-Perkin Trans.2 ,2000,6,1125-1133. Rodima,T.;Mäemets,V.;Koppel,I.;Synthesis of N-Arylsubstituted Iminophosphoranes and NMR Spectroscopic Investigation of their Acid-Base Properties in Acetonitrile,J.Chem.SocPerkin Trans.1.2000,16,2637-2644. |
viimati muudetud: 10.08.2005
| Curriculum Vitae (CV) | ||
| 1. | First Name | Ilmar |
| 2. | Surname | Koppel |
| 3. | Institution | Istitute of Chemicsl Physics,University of Tartu |
| 4. | Position | extraordinary professor |
| 5. | Date of birth | 16.01.1940 (day.month.year) |
| 6. | Education | Graduated from Chemistry Department,University of Tartu,1963,cum laude |
| 7. | Research and professional experience |
1967-1975,senior researcher,Laboratory of Chemical Kinetics and Catalysis(LCKC),University of Tartu(UT) 1976-1987,Head,LCKC,UT 1988-1992,Professor&Head,Chair of Analytical Chemistry,UT 1992-2005,Professor and Head,Institute of Chemical Physics,UT 2001-2005.Chairman,Department of Chemistry,UT 2005-present,Extraordinary Professor,UT 2004-Head of Division of Biology,geology,chemistry,Estonian Academy of Sciences 1996/1997-Founding Head,Centre of Technology,UT 2002-present,Head,Centre of Excellence in Chemistry and Materials Science,UT 1974/1975-postdoc,University of California,Irvine(UCI) 1978/1979,Visiting Professor,University of British Columbia 1981/82,UCI,Visiting Professor, 1989/90,Visiting Professor,UCI 1994,Visiting Professor,CSIC,Madrid 1999,Visiting Professor,Kyushu University 1993,1994,1995,1996,1998,1999 Shorter visits as researcher to different universities(UCI,Erlangen,Freiburg,Uppsala,Bremen,Madrid,etc. |
| 8. | Academic degree | PhD(Cand,physical chemistry) DSc(physical chemistry) |
| 9. | Dates and sites of earning the degrees |
1969,University of Tartu 1987,Institute of Chemical Physics,Academy of Sciences,Moscow |
| 10. | Honours/awards | Member,Estonian Academy of Sciences,1993- Estonian State Prize in Chemistry and Molecular Biology,1998 Estonian State Prize for long-time outstanding research,2005 |
| 11. | Research-administrative experience |
Member,Commission on Estonian State Prizes,1997-2004 Board Member of the Estonian Science Foundation,1997-2003,2005-up to date Member,Council of University of Tartu,2001-2003 National delegate for ESF PESC,2002-2005 Head,Laboratory of Chemical Kinetics and Catalysis,UT,1976-1987 Head,Institute of Chemical Physics,UT,1992-2005 Founding Head,Centre of Strategic Competence,UT,1996-1997 Chairman,Chemistry Department,UT,2001-2005 Head,Centre of Excellence in Chemistry and Materials Science,UT,2002-up to date Steering Committee of PHARE HESR programme,1995-1999 Head,Chair of Analytical Chemistry,1987-1992 |
| 12. | Supervised dissertations |
mihkel kerikmäe, PhD, 2004, superv. ilmar koppel,mihhail danilkin. Some luminescent materials for dosimetric applications and physical research. Tartu Ülikool ivari kaljurand, PhD, 2003, superv. ilmar koppel,ivo leito. Self-consistent acidity scales of neutral and cationic Brönsted acids in acetonitrile and tetrahydrofuran. Tartu Ülikool mare piirsalu, PhD, 2003, superv. ilmar koppel,vilve nummert. Substituent,temperature and solvent effects on the alkaline hydrolysis of substituted phenyl and alkyl esters of benzoic acid. Tartu Ülikool koit herodes, PhD, 2002, superv. ilmar koppel. Solvent effects on UV-vis absorption spectra of some solvatochromic substances in binary solvent mixtures;the preferential solvation model. Tartu Ülikool ivar koppel, PhD, 2001, superv. ilmar koppel,peeter burk. Quantum chemical study of acidity of strong and superstrong Brönsted acids. Tartu Ülikool katrin kollist, PhD, 2001, superv. ilmar koppel,uuve kirso. Interactions between polycyclic aromatic compounds and humic substances. Tartu Ülikool natalia palm, PhD, 2001, superv. ilmar koppel,viktor palm. Specification of the minimum,sufficient and significant set of descriptors for general description of solvent effects. Tartu Ülikool viljar pihl, PhD, 2001, superv. ilmar koppel. The study of the substituent and solvent effects on the acidity of OH and CH acids. Tartu Ülikool ivo leito, PhD, 1997, superv. ilmar koppel. Studies of Brönsted acid-base equilibria in water and non-aqueous media. Tartu Ülikool vahur mäemets, PhD, 1997, superv. ilmar koppel. The 17O and 1H nuclear magnetis resonance study of H2O in individual solvents and its charged clusters in aqueous solutions of electrolytes. Tartu Ülikool peeter burk, DSc, 1994, superv. ilmar koppel. Theoretical Study of Gas-Phase Acid-Base Equilibria. Tartu Ülikool rein pikver, cand, 1986, superv. ilmar koppel,endel lippmaa. The Influence of Structure onthe Ionisation Potentials of Carbonyl Compounds. Tartu Ülikool, Uldo Mölder, cand, 1984, superv. ilmar koppel. The Influence of Structure on the Ionisation Potentials of Compounds with Lone Electron Pairs. Tartu Ülikool |
| 13. | Current research program | Acid-base equilibria in the gas phase and solution,chemistry and design of superacids and -bases,solvent effects in chemistry,quantum chemical calculations (ab initio,DFT)of electronic structure and reactivity of chemical compounds,molecular design,photoelectron spectroscopy: Ca 250 publications |
| 14. | Current grant funding | Estonian Science Foundation #5226,The Study of the Acidity and Basicity of Strong and Superstrong Brönsted Acids and Bases,2005,242000EEK,PI-I.Koppel Targeted financing 0182552s03,The Experimental and Theoretical Study of Chemical Reactivity and Properties of Chemical Compounds,PI-I.Koppel,2005 2530000EEK |
| 15. | List of most important publications |
Kütt,A.;Leito,I.,Kaljurand,I.;Sooväli,L.;Vlasov,V.M.;Yagupolskii,L.M.,Koppel,I.A.A Comprehensive Self-Consistent Spectrophotometric Acidity Scale of Neutral Brönsted Acids in Acetonitrile,J.Org.Chem.,2006,71,2829-2838. Nummert,V.,Piirsalu,M.,Mäemets,V.,Koppel,I.,Kinetic Study of Hydrolysis of Benzoates.Part XXV.Ortho Substituent Effect in Alkaline Hydrolysis of Phenyl Esters of Substituted Benzoic Acids in Water,Collect.Czech.Chem.Commun.2006,71,#1,107-128 Sooväli,L.,Rodima,T.,Kaljurand,I.,Kütt,A.,Koppel,I.A.,Leito,I.,Basicity of some P1 Phosphazenes in Water and in Aqueous Surfactant Solution,Org.Biomol.Chem.2006,4,2100-2105. A.A.Kolomeitsev,I.A.Koppel,T.Rodima,J.Barten,E.Lork,G-V.Röschenthaler,I.Kaljurand,A.Kütt,I.Koppel,V.Mäemets,I.Leito,Guanidinophosphazenes:Design,Synthesis,and Basicity in THF and in the Gas Phase,J.Am.Chem.Soc.,2005,127,17656-17666 Herodes,K.;Leito,I.;Koppel,J;Reichardt,C.;Koppel,I.A.;UV-vis Spectrophotometric Study of the Hydrophilic and Solvatochromic 4-(2,6-diphenyl-4-(pyridin-4-yl)-pyridinium-1-yl)-2,6-bis(pyridin-3-yl)phenolate betaine Dye in Aqueous tetra-n-butylammonium bromide.,J.Phys.Org.Chem.,2005,18,1013-1017 Kaljurand,I.;Kutt,A.;Soovali,L.;Rodima,T.;Maemets,V.;Leito,I.;Koppel,I.A.,Extension of the Self-consistent Spectrophotometric Scale in Acetonitrile to a Full Span of 28 pKa Units:Unification of Different Basicity Scales,J.Org.Chem.,2005,70,1019-1028 Kaljurand,I.;Leito,I.;Rodima,T.;Kütt,A.;Pihl,A.;Rõõm,E.-I.;Sooväli,L.;Mäemets,V.;Pihl,V.;Koppel,I.A.;Mishima,M.;Vlasov,V.M.;Yagupolskii.L.M.;.Self-Consistent Bronsted Acidity and Basicity Scales in Nonaqueous Solvents,KISPOC-XI,Fukuoka ,September 12-15,2005,Proceedings,pp 89-94 Leito,I.;Kaljurand,I.;Rodima,T.;Kütt,A.;Pihl,A.;Rõõm,E.-I.;Sooväli,L.;Mäemets,V.;Pihl,V.;Koppel,I.A.;Self-Consistent Acidity and Basicity Scales in Nonaqueous Solvents,Proc.Estonian Acad.Sci.,2005,54,94-115. Nummert,V.;Piirsalu,M.;Lepp,M.;Mäemets,V.;Koppel,I.Kinetic Study of Alkaline Hydrolysis of Substituted Phenyl Tosylates.XXII.Variation of Ortho Substituent Effect With Solvent, Coll.Czech.Chem.Comm.2005,70,18-222. Nummert,V.;Piirsalu,M;Mäemets,V.;Koppel,I.;Kinetic Study of Hydrolysis of Benzoates.Part XXIV,Variation of the Ortho Substituent Effect With Solvent in the Alkaline Hydrolysis of Substituted Phenyl Benzoates,J.Phys.Org.Chem.2005,18,1138-1144 Ragnarsson,U.;Grehn,L;Koppel,J.;Loog,O.;Tsubrik,O.;Mäeorg,U.;Koppel I.A.;Acidity of di-and diprotected Hydrazine Derivatives in Dimethylsulfoxide and Aspects of their Alkylation,J.Org.Chem.,2005,70,5916-5921 Abboud,J.-L.;Alkorta,I.;Burk,P.;Davalos,J.,Z.;Quintanilla,E.;Della,E.;Koppel,I.A.;Koppel I.,The Enormous Apparent Gas-Phase Acidity of Cubylamine.;Chem.Phys.Lett.;2004,398,560-563. Mölder,U.;Burk,P.;Koppel,I.A.,Quantum Chemical Calculations of Linear Cumulene Chains,J.Mol.Struct(Theochem),2004,712,81-89. Abboud,J.-L.;Koppel,I.A.;Davalos,J.Z.; Burk,P.;Koppel I.;Quintanilla,E.,Protonation of the Cubane in the Gas Phase:A High-Level Ab initio and DFT Study,Angew.Chem.Int.Edit.,2003,42/19,1044-1046 Abboud,J.-L.M.;Koppel,I.A.;Alkorta,I.,Della,E.;Müller,P.;Davalos,J.Z.;Burk,P.;Koppel,I.;Pihl,V.;Quintanilla,E.;Stereoelectronic,Strain,and Medium Effects on the Protonation of Cubylamine,a Janus-like Base.;Angew.Chem.Int.Ed.,2003,42/20,2281-2285. Burk,P.;Leito,I.;Koppel,I.;Koppel,I.A.;Superacidity and Superbasicity of Neutral Bronsted Acids and Bases,KISPOC-X,Fukuoka,Sept.30-Oct 3,Proceedings,pp 19-24 Herodes,K.;Koppel,J.;Reichardt,C.;Koppel,I.A.;UV-visible spectroscopic study of the hydrophilic4-[2,6-diphenyl-4-(pyridin-4-yl]-2,6-bis/pyridin-3-yl)phenolate betaine dye in eight binary solvent mixtures,J.Phys.Org.Chem.,2003,16,626-632 Kaljurand,I.;Rodima,T.;Pihl,A.;Maemets,V.;Leito,I.;Koppel,I.A.;Mishima,M.,Acid-Base Equilibria in Nonpolar Media.4.Expanding the Self-consistent Basicity Scale in THF Medium.Gas-phase Basicities of Phosphazenes,J.Org.Chem.,2003,68,9988-9993. Kaljurand,I.;Rodima,T.;Pihl,A.;Rõõm,E.-I.;Leito,I.;Kütt,A.;Sooväli,L.;Mäemets,V.;Koppel,I.A.;Mishima,M.;Yagupolskii,L.M.,Extending Acidity and Basicity Scales in Nonaqueous Solvents and Gas-phase,KISPOC-X,Fukuoka,Sept 30-Oct 3,2003,Proceedings,pp 216-221 Rõõm,E.-I.;Kaljurand,I.;Leito,I.;Rodima,T.;Koppel,I.A.;Vlasov,V.M.,Acid-Base Equilibria in Nonpolar Media.3.Expanding the Spectrophotometric Acidity Scale in Heptane,J.Org.Chem.,2003,68,7795-7799. Koppel,I.A.;Burk,P.;Koppel,I.;Leito,I.;Generalized Principle of Designing of Neutral Superstrong Brönsted Acids,J.Am.Chem.Soc.,2002,124,5594-5600. Mõlder,U.;Pikver,R.;Koppel,I.I.;Burk,P.;Koppel ,I.A.;Photoelectron Spectra of Molecules.12.Vinyl,Allyl,and Phenyl Ethers and Sulfides.,J.Mol.Struct(Theochem),2002,579,205-220. Rodima,T.;Kaljurand,I.;Pihl,A.;Mäemets,V.;Leito,I.;Koppel,I.A.;Acid-base Equilibria in Nonüpolar Media.2.Self-Consistent Basicity Scale in THF Solution Ranging from 2-Methoxypyridine to EtP1(pyr) Phosphazene.,J.Org.Chem.,2002,67,1873-1881. Yagupolskii,L.M.;Petrik,V.N.;Kondratenko,N.V.;Sooväli,L.;Kaljurand,I.;Leito,I.;Koppel,I.A.,The Immense Acidifying effect of the Supersubstituent =NSO2CF3 on the Acidity of Amides and amidines of Benzoic Acid in Acetonitrile,J.Chem.Soc.Perkin Trans 2,2002,1950-1955. Burk,P.;Sillar,K.;Koppel,I.A.;Gas-Phase Basicities and Proton Affinities of Alkali Metal Oxides and Hydroxides,A theoretical Study,;J.Mol.Struct.(Theochem),2001,54,1-3,223-231 Koppel,I.A.;Koppel,J.;Leito,I.;Koppel,I.;Mishima,M.;Yagupolskii,L.M.;The Enormous Acidifying Effect of Supersubstituents =NSO2CF3 on Acidity of Derivatives of Benzenesulfonamide and para-toluenesulfonamide in the gas-phase and in Dimethylsulfoxide,J.Chem.Soc.Perkin 2,2001,229-232. Koppel,I.A.;Schwesinger,R.;Breuer,T.;Burk,P.;Herodes,K.;Koppel,I.I.;Leito,I.;Mishima,M., Intrinsic Basicities of Phosphorus Imines and Ylides.A Theoretical Study,J.Phys.Chem.A,2001,105,9575-9586. Mölder,U.;Burk,P.;Koppel,I.A.;Quantum Chemical Calculations of Geometries and Gas-Phase Deprotonation Energies of Linear Polyyne Chains,Int.Quant.Chem.;2001,82,73-85. Burk,P.;Koppel,I.A.;Koppel,I.;Leito,I.;Travnikova,O.;Critical Test of Performance of B3LYP Functional for Prediction of Gas-Phase Acidities and Basicities,Chem.Phys.Lett.,2000,232,5-6,482-489. Kaljurand,I.;Rodima,T.;Leito,I.;Koppel,I.A.;Schwesinger,R.;self-Consistent Spectrophotometric Basicity Scale in Acetonitrile Covering range Between Pyridine and DBU,J.Org.Chem.,2002,65,6202-6208. Koppel,I.A.;Burk,P.;Koppel,I.;Leito,I.;Sonoda,T.;Mishima,M.;Gas-Phase Acidities of Some Neutral Superacids:A DFT and Ab initio Study,J.Am.Chem.Soc.,2000,122,5114-5124. Koppel I.A.;Koppel,J.;Pihl,V.;Leito,I.;Mishima,M.;Vlasov,V.M.;Yagupolskii,L.M.;Taft,R.W.;Comparison of Brönsted Acidities of Neutral CH acids in Gas Phase and Dimethyl Sulfoxide,J.Chem.Soc,-Perkin Trans.2 ,2000,6,1125-1133. Rodima,T.;Mäemets,V.;Koppel,I.;Synthesis of N-Arylsubstituted Iminophosphoranes and NMR Spectroscopic Investigation of their Acid-Base Properties in Acetonitrile,J.Chem.SocPerkin Trans.1.2000,16,2637-2644. |
last updated: 10.08.2005
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