| title: | Alkaki Metal Ion Affinities in the Gas Phase |
|---|---|
| reg no: | ETF5196 |
| project type: | Estonian Science Foundation research grant |
| subject: |
1.8. Molecular Biology |
| status: | completed |
| institution: | University of Tartu |
| head of project: | Peeter Burk |
| duration: | 01.01.2002 - 31.12.2005 |
| description: | 1. Generation of the web-based publicly available database of critically evaluated alkali metal cation affinities and basicities 2. Finding and calibrating of the theoretical calculation methods for reliable estimation of alkali metal cation affinities 3. Comparison of the gas-phase alkali metal cation affinities and proton affinities for a different families of Lewis bases 4. Construction of alkali metal cation affinity scales for anionic bases 5. Theoretical modeling of the cooperative effects (influence of the distance and orientation of coordination sites, role of non-classical coordination, and flexibility of the ligands |
| project group | ||||
|---|---|---|---|---|
| no | name | institution | position | |
| 1. | Peeter Burk | Tartu University, Institute of Chemical Physics | associate professor | |
| 2. | Urmas Muinasmaa | Tartu University | Ph. D. student | |
| 3. | Kaido Sillar | Tartu University | Ph. D. student | |
| 4. | Kaido Tämm | Tartu University | Ph. D. student | |