| title: | Complexation equilibria between alkali metal cations and Lewis bases |
|---|---|
| reg no: | SF0182570s03 |
| project type: | targeted financing |
| subject: |
1.6-1.9. Chemistry and Molecular Biology |
| status: | accepted |
| institution: | University of Tartu |
| head of project: | Peeter Burk |
| duration: | 01.01.2003 - 31.12.2007 |
| description: | The current project focuses on the following goals: 1. Generation of the web-based publicly available database of critically evaluated alkali metal cation affinities and basicities 2. Finding and calibrating of the theoretical calculation methods for reliable estimation of alkali metal cation affinities 3. Comparison of the gas-phase alkali metal cation affinities and proton affinities for different families of Lewis bases 4. Construction of alkali metal cation affinity scales for anionic bases 5. Theoretical modeling of the cooperative effects (influence of the distance and orientation of coordination sites, role of non-classical coordination, and flexibility of the ligands |
| project group | ||||
|---|---|---|---|---|
| no | name | institution | position | |
| 1. | Peeter Burk | University of Tartu | ||
| 2. | Martin Kutsar | University of Tartu | magistrant | |
| 3. | Urmas Muinasmaa | University of Tartu | doktorant | |
| 4. | Vahur Mäemets | University of Tartu | teadur | |
| 5. | Kaido Sillar | University of Tartu | teadur | |
| 6. | Jaana Tammiku-Taul | University of Tartu | doktorant | |
| 7. | Sven Tamp | University of Tartu | doktorant | |
| 8. | Kristo Taul | University of Tartu | magistrant | |
| 9. | Kaido Tämm | University of Tartu | doktorant | |